Interpretations of the real time scattering experiment for polystyrene melts during stress relaxation
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Fast-track communication Meeting experimental challenges to physics of network glasses: Assessing the role of sample homogeneity
We introduce a Raman profiling method to track homogenization of GexSe100−x melts in real time, and show that 2 g melts reacted at 950 °C in high vacuum homogenize in 168 h on a scale of 10μm. Homogenization of melts is precursive to self-organization of glasses. In the present glasses, compositional variation of Raman active corner-sharingmode frequency of GeSe4 units,molar volumes, and the en...
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We present a differential constitutive model of stress relaxation in polydisperse linear polymer melts and solutions that contains contributions from reptation, contour-length fluctuations, and chain stretching. The predictions of the model during fast start-up and steady shear flows of polymer melts are in accord with experimental observations. Moreover, in accordance with reported experimenta...
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Neutron scattering and computer simulations are powerful tools for studying structural and dynamical properties of condensed matter systems in general and of polymer melts in particular. When neutron scattering studies and quantitative atomistic molecular dynamics simulations of the same material are combined, synergy between the methods can result in exciting new insights into polymer melts no...
متن کاملPii: S0377-0257(02)00134-9
Filament stretching experiments are used to follow the evolution in the flow-induced birefringence (FIB) and the tensile force in polymeric fluid threads undergoing uniaxial elongation. The tests are performed with several monodisperse polystyrene solutions spanning concentrations from 0.025 to 12 wt.%, and the measurements are used to investigate the extent of hysteresis in the polymeric stres...
متن کاملStress relaxation in entangled melts of unlinked ring polymers.
Stress relaxation in unlinked ring polymer melts poses an important challenge to our theoretical understanding of entangled polymer dynamics. Recent experiments on entangled unlinked ring melts show power-law stress relaxation with no hint of a rubbery plateau, usually the hallmark of entangled polymers. Here we present a theory for stress relaxation in rings analogous to the successful approac...
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تاریخ انتشار 2016